UNOCCUPIED ELECTRONIC STATES OF POTASSIUM AND SODIUM ON Ag(110)

Abstract

Unoccupied electronic states induced by alkali adsorption on a Ag(11O) surface were investigated by inverse photoemission. In addition to electrostatically induced level shifts the formation of energy bands in periodic overlayers was monitored. Despite their chemical similarity considerable differences exist between potassium and sodium induced empty electronic states. The relation of the observed unoccupied bands to the two-dimensional bandstructure of an unsupported alkali metal layer is discussed.